Pinned
Cornellab
1,167 posts
Cornellab
@CornellaLab
Synthesis focused. Catalysis driven. At Max-Planck-Institut für Kohlenforschung
- Yes, it is a bismuthinidene. Yes, it is stable. Yes, it is a triplet. Yes, it is non-magnetic. chemrxiv.org/engage/chemrxi…
- Ni(Fstb)3. An air-stable source of Ni(0). Thinking outside the (Glove)box. @LNattmann @rsaeb2 nature.com/articles/s4192…
- Catalytic synthesis of phenols with N2O. An enormous effort spearheaded by @FranckF1476 !Congrats to all the authors involved. nature.com/articles/s4158…
- Bi-catalyzed radical catalysis with redox-active esters. Congrats to everyone involved!
- A new story on Bismuth Redox Catalysis: this time, triflate and nonaflate as nucleophiles. Great work from @uri_planas and Vytautas! pubs.acs.org/doi/pdf/10.102…
- Expanding the horizons for bismuth as a redox catalyst. Now for cyclopropanation. @J_A_C_S pubs.acs.org/doi/epdf/10.10… with @ShengyangN & @DavideSpinnato2
- The fluorination of boronic esters through bismuth redox catalysis is now out in Science.Heavy cycle! Bismuth redox catalysis from @CornellaLab in this week’s @ScienceMagazine science.sciencemag.org/content/367/64…
- Deaminative Chlorination of Aminoheterocycles: bringing the best of the Vilsmeier disconnection to late-stage. 5- and 6-member rings. >20 heterocyclic scaffolds. Sneak peak of what @ChemRxiv chemrxiv.org/articles/prepr… @ClementGhiazza, Teresa and Alejandro!
- Single electron oxidative addition at Bismuth unlocks radical cross-coupling catalysis in C-N couplings. Work led by @mato_mauro. Great job from all involved! chemrxiv.org/engage/chemrxi…
- Reporting in @J_A_C_S: low-valent Bi redox catalysis via elementary organometallic steps: catalytic hydrodefluorination. Excellent work by Yue (@YPYuePang) Markus (@MrIrieman), Nils and Felix! pubs.acs.org/doi/10.1021/ja…
- Ni(4-tBustb)3: More stable. More robust. More nickel. @Orgmet_ACS @LNattmann pubs.acs.org/doi/10.1021/ac…
- Honored to be part of these outstanding group. Thanks to all the co-workers at the @CornellaLab @maxplanckpress for their dedication and passion during these years! 👍🏽Replying to @cenmagJosep Cornella is a #catalysis chemist looking to make reactions faster and easier. bit.ly/2PSyjK0 #cenT12
- 🚨Calling medicinal chemists🚨: A Suzuki het-het coupling sometimes does not require complex ligands. An air stable Ni would do. Amazing work from @rsaeb2 Rakan Saeb and Byeongdo Roh. onlinelibrary.wiley.com/doi/10.1002/an…
