1 FUNDAMENTALS OF RADIATIVE TRANSFER 1 1.1 The Electromagnetic Spectrum; Elementary Properties of Radiation 1 1.2 Radiative Flux 2 Macroscopic Description of the Propagation of Radiation 2 Flux from an Isotropic Source-The Inverse Square Law 2 1.3 The Specific Intensity and Its Moments 3 Definition of Specific Intensity or Brightness 3 Net Flux and Momentum Flux 4 Radiative Energy Density 5 Radiation Pressure in an Enclosure Containing an Isotropic Radiation Field 6 Constancy of Specific Zntensiw Along Rays in Free Space 7 Proof of the Inverse Square Law for a Uniformly Bright Sphere 7 1.4 Radiative Transfer 8 Emission 9 Absorption 9 The Radiative Transfer Equation 11 Optical Depth and Source Function 12 Mean Free Path 14 Radiation Force 15 1.5 Thermal Radiation 15 Blackbody Radiation 15 Kirchhof's Law for Thermal Emission 16 Thermodynamics of Blackbody Radiation 17 The Planck Spectrum 20 Properties of the Planck Law 23 Characteristic Temperatures Related to Planck Spectrum 25 1.6 The Einstein Coefficients 27 Definition of Coefficients 27 Relations between Einstein Coefficients 29 Absorption and Emission Coefficients in Terms of Einstein Coefficients 30 1.7 Scattering Effects; Random Walks 33 Pure Scattering 33 Combined Scattering and Absorption 36 1.8 Radiative Diffusion 39 The Rosseland Approximation 39 The Eddington Approximation; Two-Stream Approximation 42 PROBLEMS 45 REFERENCES 50 2 BASIC THEORY OF RADIATION FIELDS 51 2.1 Review of Maxwell’s Equations 51 2.2 Plane Electromagnetic Waves 55 2.3 The Radiation Spectrum 58 2.4 Polarization and Stokes Parameters 62 Monochromatic Waves 62 Quasi-monochromatic Waves 65 2.5 Electromagnetic Potentials 69 2.6 Applicability of Transfer Theory and the Geometrical Optics Limit 72 PROBLEMS 74 REFERENCES 76 3 RADIATION FROM MOVING CHARGES 77 3.1 Retarded Potentials of Single Moving Charges: The Lienard-Wiechart Potentials 77 3.2 The Velocity and Radiation Fields 80 3.3 Radiation from Nonrelativistic Systems of Particles 83 Larmor's Formula 83 The Dipole Approximation 85 The General Multipole Expansion 88 3.4 Thomson Scattering (Electron Scattering) 90 3.5 Radiation Reaction 93 3.6 Radiation from Harmonically Bound Particles 96 Undriven Harmonically Bound Particles 96 Driven Harmonically Bound Particles 99 PROBLEMS 102 REFERENCE 105 4 RELATIVISTIC COVARIANCE AND KINEMATICS 106 4.1 Review of Lorentz Transformations 106 4.2 Four-Vectors 113 4.3 Tensor Analysis 122 4.4 Covariance of Electromagnetic Phenomena 125 4.5 A Physical Understanding of Field Transformations 129 4.6 Fields of a Uniformly Moving Charge 130 4.7 Relativistic Mechanics and the Lorentz Four-Force 136 4.8 Emission from Relativistic Particles 138 Total Emission 138 Angular Distribution of Emitted and Received Power 140 4.9 Invariant Phase Volumes and Specific Intensity 145 PROBLEMS I48 REFERENCES 154 5 BREMSSTRAHLUNG 155 5.1 Emission from Single-Speed Electrons 156 5.2 Thermal Bremsstrahlung Emission 159 5.3 Thermal Bremsstrahlung (Free-Free) Absorption 5.4 Relativistic Bremsstrahlung 163 PROBLEMS 165 REFERENCES I46 6 SYNCHROTRON RADIATION 167 6.1 Total Emitted Power 167 6.2 Spectrum of Synchrotron Radiation: A Qualitative Discussion 169 6.3 Spectral Index for Power-Law Electron Distribution 173 6.4 Spectrum and Polarization of Synchrotron Radiation: A Detailed Discussion 175 6.5 Polarization of Synchrotron Radiation 180 6.6 Transition from Cyclotron to Synchrotron Emission 181 6.7 Distinction between Received and Emitted Power 184 6.8 Synchrotron Self-Absorption 186 6.9 The Impossibility of a Synchrotron Maser in Vacuum 191 PROBLEMS 192 REFERENCES 194 7 COMPTON SCATTERING 195 7.1 Cross Section and Energy Transfer for the Fundamental Process 195 Scattering from Electrons at Rest 195 Scattering from Electrons in Motion: Energy Transfer 197 7.2 Inverse Compton Power for Single Scattering 199 7.3 Inverse Compton Spectra for Single Scattering 202 7.4 Energy Transfer for Repeated Scatterings in a Finite, Thermal Medium: The Compton Y Parameter 208 7.5 Inverse Compton Spectra and Power for Repeated Scatterings by Relativistic Electrons of Small Optical Depth 211 7.6 Repeated Scatterings by Nonrelativistic Electrons: The Kompaneets Equation 213 7.7 Spectral Regimes for Repeated Scattering by Nonrelativistic Electrons 216 Modified Blackbody Spectra; y<<1 218 Wien Spectra; y>>1 219 Unsaturated Comptoniration with Soft Photon Input 221 PROBLEMS 223 REFERENCES 223 8 PLASMA EFFECTS 224 8.1 Dispersion in Cold, Isotropic Plasma 224 The Plasma Frequency 224 Group and Phase Velocity and the Index of Refraction 227 8.2 Propagation Along a Magnetic Field; Faraday Rotation 229 8.3 Plasma Effects in High-Energy Emission Processes 232 Cherenkov Radiation 233 Razin Effect 234 PROBLEMS 236 REFERENCES 237 9 ATOMIC STRUCTURE 238 9.1 A Review of the Schrodinger Equation 238 9.2 One Electron in a Central Field 240 Wave Functions 240 Spin 243 9.3 Many-Electron Systems 243 Statistics: The Pauli Principle 243 Hartree-Fock Approximation: Configurations 245 The Electrostatic Interaction; LS Coupling and Terms 247 9.4 Perturbations, Level Splittings, and Term Diagrams 248 Equivalent and Nonequivalent Electrons and Their Spectroscopic Terms 248 Parity 251 Spin-Orbit Coupling 252 Zeeman Effect 256 Role of the Nucleus; Hyperfine Structure 257 9.5 Thermal Distribution of Energy Levels and Ionization 259 Thermal Equilibrium: Boltzmann Population of Levels 259 The Saha Equation 260 PROBLEMS 263 REFERENCES 266 10 RADIATIVE TRANSITIONS 267 10.1 Semi-Classical Theory of Radiative Transitions 267 The Electromagnetic Hamiltonian 268 The Transition Probability 269 10.2 The Dipole Approximation 271 10.3 Einstein Coefficients and Oscillator Strengths 274 10.4 Selection Rules 278 10.5 Transition Rates 280 Bound-Bound Transitions for Hydrogen 280 Bound-Free Transitions (Continuous Absorption) for Hydrogen 282 Radiative Recombination- Milne Relations 284 The Role of Coupling Schemes in the Determination off Values 286 10.6 Line Broadening Mechanisms 287 Doppler Broadening 287 Natural Broadening 289 Collisional Broadening 290 Combined Doppler and Lorentz Profiles 291 PROBLEMS 291 REFERENCES 292 11 MOLECULAR STRUCTURE 294 11.1 The Born-Oppenheimer Approximation: An Order of Magnitude Estimate of Energy Levels 294 11.2 Electronic Binding of Nuclei 296 The H_2^+ Zon 297 The H_2 Molecule 300 11.3 Pure Rotation Spectra 302 Energy Levels 302 Selection Rules and Emission Frequencies 304 11.4 Rotation-Vibration Spectra 305 Energy Levels and the Morse Potential 305 Selection Rules and Emission Frequencies 306 11.5 Electronic-Rotational-Vibrational Spectra 308 Energy Levels 308 Selection Rules and Emission Frequencies 308 PROBLEMS 311 REFERENCES 312 SOLUTIONS 313 INDEX 375