A canonical question is a broad question/answer pair that is intended to be a duplicate target for commonly asked questions, or address a commonly found problem (for Meta Stack Overflow). The intent is that we aren't posting variations on the same question/answer pair over and over again.
For example, here's one with 2,654 dupe targets (and that doesn't include the deleted ones, if I had to guess):
What is a NullReferenceException, and how do I fix it?
Here's one I wrote on Meta:
Why is "Can someone help me?" not an actual question?
Note the pattern. The question addresses a specific type of problem, or in other words, doesn't get into specific code or posts. The answer is usually a self-answer, and attempts to give general guidance in regards to the question.
You didn't ask what piece of canonical posts was confusing you, but these kinds of posts are what we refer to when we use the term.