ASTM E1787 Sheathed Thermocouple Calibration Testing
Anionic impurities in caustic soda and caustic potash are monitored by manufacturers and users for quality control of the products. Anions of primary interest are chloride, chlorate, and sulfate. The ASTM E1878-16 test method can determine precision estimates for these three impurities.

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- Overview
- Scope, Applications, and Benefits
- Test Process
- Specifications
- Instrumentation
- Results and Deliverables
Overview
ASTM E1787-16 provides a test method for determining inorganic anions present in caustic soda (NaOH) and caustic potash (KOH) using ion chromatography. These anions can affect product quality and performance in industrial applications.
This standard is widely used in chemical industries to ensure purity and control impurities in alkaline solutions.

Scope, Applications, and Benefits
Scope
ASTM E1787-16 focuses on the quantitative analysis of anions such as chloride, sulfate, and carbonate in caustic solutions. It ensures accurate detection of impurities at low concentrations.
The test evaluates:
- Anion concentration (Cl⁻, SO₄²⁻, CO₃²⁻, etc.)
- Purity of caustic solutions
- Contamination levels
- Suitability for industrial use
- Compliance with specifications
Applications
- Chemical manufacturing
- Pulp and paper industry
- Water treatment
- Industrial cleaning solutions
- Quality control laboratories
Benefits
- High sensitivity and accuracy
- Multi-anion detection in one analysis
- Supports quality assurance
- Improves process control
- Enables comparison of batches
Test Process
Sample Preparation
Caustic solution is diluted appropriately.
1Instrument Calibration
Ion chromatograph is calibrated using standards.
2Separation and Detection
Anions are separated and detected in IC system.
3Data Recording & Evaluation
Concentrations are calculated and reported.
4Technical Specifications
| Parameter | Details |
|---|---|
| Applicable Materials | Caustic soda and caustic potash |
| Detection Range | ppm to low ppb levels |
| Analytes | Cl⁻, SO₄²⁻, CO₃²⁻, NO₃⁻, etc. |
| Eluent | Typically carbonate/bicarbonate solution |
| Measured Outputs | Anion concentration (ppm or mg/L) |
Instrumentation Used for Testing
- Ion chromatograph (IC)
- Conductivity detector
- Sample injection system
- Eluent preparation system
- Calibration standards
- Data acquisition system
Results and Deliverables
- Anion concentration report
- Purity assessment
- Chromatographic data
- Test condition summary
- ASTM compliance report
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Frequently Asked Questions
ASTM E1787-16 is a standard test method used to determine anions in caustic soda and caustic potash using ion chromatography for accurate chemical analysis.
ASTM E1787-16 is important because impurities like anions affect product quality, process efficiency, and equipment corrosion, making accurate analysis essential for industrial applications.
ASTM E1787-16 separates anions based on their interaction with a chromatographic column and detects them using conductivity measurement for precise quantification.
ASTM E1787-16 requires an ion chromatograph, sample preparation tools, calibration standards, and controlled conditions to ensure reliable and repeatable results.
Results are reported as concentrations of individual anions, typically in ppm, helping ensure product purity and compliance with industrial specifications.

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