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Made with PS CS3, work with other versions.
Credit isn't necessary.
Comments are appreciated.
Don't say that you made this tutorial.
Sorry for my bad English. ;)
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Here is the Lavigne's base image.
And Here is a larger result.

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1. Color Balance

Midtones: -34 0 0
highlights: 14 0 2

2. Selective Color

Reds: -100 34 0 0
Yellows: 100 100 100 0
Cyans: 100 -24 -100 0
Blues: 100 -100 -100 0
Whites: -100 0 0 0
Blacks: -7 0 0 0

3. Selective Color

Reds: -32 35 100 0


4. Selective Color

Reds: -83 0 38 0
Yellows: 100 0 0 0
Blues: 100 0 -100 -46


5. Selective Color

Neutrals: 25 -14 -15 -3

6. Selective Color

Reds: -47 0 0 0
Cyans: 51 -40 -13 0
Neutrals: 0 1 -6 0

Finished! :]

PSD file - Here


Other examples: