PowerDVD help?

I downloaded the trial version of PowerDVD just minutes ago, and I picked up on how to cap images.
Now, I see there is a video button but I can't click on it. Why is that?

I also have Intervideo WinDVD. Is it any similar to PowerDVD? Does it have a video capture too?

Plus, I want to make a icon like this:


Sorry, I found this on photobucket so I don't know who made it.

Thanks in advance =]

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