Know how to get this coloring effect?

Hi, i am a newbie to the community so i am not sure if I am posting this correctly or not. But here goes

Anyone know how to get this effect?

http://i3.photobucket.com/albums/y76/tynisha/love.jpg

Here is the original screencap:

http://i3.photobucket.com/albums/y76/tynisha/8-16-05_Matie4.jpg